Questions 91–100 of 650. Imported answers require independent review unless marked reviewed.

Topic practice 650 questionsPage 10 of 65

Question 26

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Among the given options, the possible product(s) that can be obtained from the following reaction is/are
Diagram for Chemistry question 26

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Question 27

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Choose the correct option(s) with regard to mechanism of the following transformation.
Diagram for Chemistry question 27

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Question 28

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Consider two non-interacting particles confined to a one-dimensional box with infinite potential barriers. Their wavefunctions are

and

and energies are

and

, respectively. The INCORRECT statement(s) about this system is/are
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Question 29

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The thermodynamic criterion/criteria for a spontaneous process is/are
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Question 30

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Xe and F

in 1:1 molar ratio when mixed in a closed flask and kept in the sunlight for a day, gave white crystals of a compound Q. Two equivalents of Q on reaction with one equivalent of AsF

gave an ionic compound X

Y

with the cation having two Xe atoms. The total number of lone pairs present on the cation X

is _____ (in integer).

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Question 31

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The total number of hyperfine lines expected in the EPR spectrum of •CH

OH (radical) is ______ (in integer). [Note: Consider all hydrogen atoms for calculation]

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Question 32

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Partial hydrolysis of a pentapeptide yields all possible tripeptides and dipeptides. The dipeptides that are obtained upon hydrolysis are given below.
Val-Ala, Gln-His, Phe-Val and Ala-Gln
The total number of tripeptides obtained that contain ‘Ala’ as one of the amino acids is____ (in integer).

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Question 33

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The specific rotation of enantiomerically pure (S)-2-butanol is +14°. The specific rotation of enantiomeric mixture of 2-butanol obtained from an asymmetric reduction of 2-butanone is found to be +7°. The percentage of (R)-2-butanol present in the reaction mixture is ______ (in integer).

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Question 34

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The ratio of the fundamental vibrational frequencies

of two diatomic molecules

and

, considering their force constants to be the same, is_______ (rounded off to two decimal places).

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Question 35

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The expressions for the vapour pressure of solid (

) and vapour pressure of liquid (

) phases of a pure substance, respectively, are

and

The triple point temperature of this substance is ____ K (in integer).

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