Questions 81–90 of 394. Imported answers require independent review unless marked reviewed.

Topic practice 394 questionsPage 9 of 40

Question 18

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Critical micellar concentration of a surfactant is 0.008 M in water at 25 °C. If the aggregation number of the micelles is 80, the concentration of the micelles (in M) present in 0.088 M aqueous solution of the surfactant at 25 °C is
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Question 19

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The order and the number of classes present in a group with the irreducible representations A₁, A₂, B₁, B₂, E₁, and E₂, are, respectively,
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Question 20

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The molecule XY₂ is microwave active and its vibration-rotation spectrum shows only P and R transitions. In the correct structure,
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Question 36

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Borax on treatment with NaOH and H₂O₂ forms X. The compound X on reaction with PhCN at 60 °C in methanol-water mixture gives Y as the major product. X and Y, respectively, are
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Question 37

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In the EPR spectrum of an aqueous solution of VSO₄ at room temperature, the total number of hyperfine splitting signals is
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Question 38

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The hapticity of allyl and Cp and the ligation mode of NO in the thermodynamically stable complexes [(ηˣ-allyl)Ru(CO)₂(NO)] and [(ηʸ-Cp)Ru(CO)₂(NO)], respectively, are (The hapticity of allyl and Cp are denoted by ηˣ and ηʸ, respectively.)
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Question 39

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In the following reactions, the structures of I, II, and III, respectively, are
Diagram for Chemistry question 39

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Question 40

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Consider the following

H-NMR (400 MHz, DMSO-d

) data of a compound:

in ppm: 3.85 (s, 6H), 6.73 (t, J = 2.2 Hz, 1H), 7.1 (d, J = 2.2 Hz, 2H), and 13.05 (brs, 1H).
The compound is
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Question 41

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Fischer presentation of D-(-)-fructose is given below.
Diagram for Chemistry question 41

The correct structure of

-L-(+)-fructofuranose is
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Question 42

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The major products X and Y in the following reaction sequence are
Diagram for Chemistry question 42

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