Questions 151–160 of 166. Imported answers require independent review unless marked reviewed.

Topic practice 166 questionsPage 16 of 17

Question 7

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The dependence of rate constant

on temperature

(in K) of a reaction is given by the expression

The activation energy of the reaction (in kJ mol

) is __________ (up to two decimal places)

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Question 8

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The lowest energy of a quantum mechanical one-dimensional simple harmonic oscillator is 300 cm

. The energy (in cm

) of the next higher level is ________________

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Question 12

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The hapticity of cycloheptatriene, (C

H

), in Mo(C

H

)(CO)

is __________

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Question 25

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The number of possible stereoisomers for cyclononene is __________

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Question 26

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The mobility of a univalent ion in aqueous solution is

at 300 K. Its diffusion coefficient at 300 K is

. The value of X is __________ (up to two decimal places)

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Question 27

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For the following consecutive first order reactions

the time (in seconds) required for Y to reach its maximum concentration (assuming only X is present at time

) is __________ (up to two decimal places)

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Question 28

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Under physiological conditions, the conversion of CO

to bicarbonate ion by carbonic anhydrase enzyme (MW = 30,000 g mol

) has a turnover number of

s

. The minimum amount of enzyme (in μg) required to convert 0.44 g of CO

to bicarbonate ions in 100 seconds is __________ (up to two decimal places)

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Question 29

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Assume 1,3,5-hexatriene to be a linear molecule and model the π electrons as particles in a one-dimensional box of length 0.70 nm. The wavelength (in nm) corresponding to the transition from the ground-state to the first excited-state is __________

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Question 30

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The standard Gibbs free energy change of the reaction shown below is −2.7 kJ mol

.
Sn(s) + Pb

= Sn

+ Pb(s)
Given that

is −0.126 V, the value of

in V is __________ (up to two decimal places)

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Question 31

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The dissociative chemisorption of X

(g) on a metal surface follows Langmuir adsorption isotherm. The ratio of the rate constants of the adsorption and desorption processes is 4.0 atm

. The fractional surface coverage of X(adsorbed) at 1.0 atm pressure is __________ (up to two decimal places)

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