Questions 21–30 of 65. Imported answers require independent review unless marked reviewed.

Topic practice 65 questionsPage 3 of 7

Question 21

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The major product obtained in the following reaction is
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Question 22

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In the two step reaction sequence given below, the starting bis-sulfone acts as
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Question 23

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The major product formed in the following photochemical reaction is
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Question 24

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The product formed in the following reaction is
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Question 25

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The number of possible stereoisomers for cyclononene is __________

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Question 26

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The mobility of a univalent ion in aqueous solution is

at 300 K. Its diffusion coefficient at 300 K is

. The value of X is __________ (up to two decimal places)

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Question 27

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For the following consecutive first order reactions

the time (in seconds) required for Y to reach its maximum concentration (assuming only X is present at time

) is __________ (up to two decimal places)

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Question 28

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Under physiological conditions, the conversion of CO

to bicarbonate ion by carbonic anhydrase enzyme (MW = 30,000 g mol

) has a turnover number of

s

. The minimum amount of enzyme (in μg) required to convert 0.44 g of CO

to bicarbonate ions in 100 seconds is __________ (up to two decimal places)

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Question 29

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Assume 1,3,5-hexatriene to be a linear molecule and model the π electrons as particles in a one-dimensional box of length 0.70 nm. The wavelength (in nm) corresponding to the transition from the ground-state to the first excited-state is __________

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Question 30

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The standard Gibbs free energy change of the reaction shown below is −2.7 kJ mol

.
Sn(s) + Pb

= Sn

+ Pb(s)
Given that

is −0.126 V, the value of

in V is __________ (up to two decimal places)

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