Questions 171–180 of 668. Imported answers require independent review unless marked reviewed.

Topic practice 668 questionsPage 18 of 67

Question 124

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XE-FNAT2 marksNeeds review
If a given poly(ethylene) sample with specific volume,

shows: specific volume of the crystalline fraction,

and specific volume of the amorphous fraction,

, then the % crystallinity (based on mass fraction) of the poly(ethylene) sample is ______ % (rounded off to the nearest integer).

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Question 125

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XE-FNAT2 marksNeeds review
The glass transition temperature (

) of poly(2,6-dimethyl-p-phenylene oxide) (PPO) is 206 °C and the

of poly(styrene) (PS) is 90 °C. The

of a 50/50 (wt/wt) miscible blend of PPO/PS is ______ °C (rounded off to the nearest integer).

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Question 126

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XE-FNAT2 marksNeeds review
A unidirectional composite is prepared using 70% by volume of epoxy matrix and 30% by volume of carbon fibre. The elastic modulus of the epoxy matrix is 3.5 GPa and the elastic modulus of the carbon fibre is 350 GPa. The longitudinal elastic modulus of the composite is ______ GPa (rounded off to the nearest integer).

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Question 127

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XE-FNAT2 marksNeeds review
Polyamide 66 is prepared by the condensation polymerization of 0.08 mol of hexamethylene diamine with 0.08 mol of adipic acid. At the end of the polymerization reaction, the reaction product contained 0.002 mol of unreacted carboxylic acid groups. The molecular weight of the repeat unit of polyamide 66 is 226 g mol

. The number-average molecular weight (

) of the polyamide 66 in the reaction product is ______ g mol

(rounded off to the nearest integer).

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Question 128

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XE-FNAT2 marksNeeds review
A monodisperse polymer sample of molecular weight 10,000 g mol

is mixed with another monodisperse sample of the same polymer of molecular weight 50,000 g mol

. The total mass of the mixture is 1,000 g and the total number of moles of the polymer in the mixture is 0.04 mol. The weight-average molecular weight (

) of the polymer mixture is ______ g mol

(rounded off to the nearest integer).

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Question 129

Open question
XE-FNAT2 marksNeeds review
For a polymer solution, the dependence of viscosity (

) on shear rate (

) is described by the three-parameter Carreau model given by

where,

,

, and

are the three parameters of the model. Here, all three parameters are positive quantities. As the shear rate increases from 1 s

to 100 s

, the viscosity of the polymer solution decreases by a factor of 10. For a polymer solution with

and

Pa s, the value of the parameter

is ______ s (rounded off to two decimal places).

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Question 130

Open question
XE-FNAT2 marksNeeds review
The dilute solution viscometry data for two samples of a polymer with two different molecular weights are shown in the figure, where

has been plotted against

. Here,

is the specific viscosity and

is the mass concentration of the polymer solution. The slopes and intercepts of the plots for both the samples are shown in the figure. The plotted data for both samples are described by the Huggins equation of dilute solution. The value of the Mark-Houwink constant ‘a’ for both polymer samples is 0.5. The ratio of the viscosity-average molecular weight (

) of polymer sample 1 to that of polymer sample 2, i.e.,

, is ______ (rounded off to two decimal places).
Diagram for Engineering Sciences question 130


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Question 131

Open question
XE-FNAT2 marksNeeds review
The linear viscoelastic behavior of a polymer is described by the Kelvin-Voigt model consisting of a spring element of elastic modulus 10 MPa in parallel with a dashpot of viscosity 3.6 × 10

Pa s. A fixed stress of 40 MPa is suddenly applied to the polymer and maintained thereafter. The value of the strain after one hour from the sudden application of the stress is ______ (rounded off to two decimal places).

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Question 140

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XE-GNAT1 markNeeds review
Thermal resistance constant (z-value) is defined as the change in temperature required to reduce the decimal reduction time of a microorganism by __________ percent (Answer in integer).

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Question 151

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XE-GNAT2 marksNeeds review
A 10 kg tomato pulp is concentrated from an initial moisture content of 90% (wet weight basis) to 35% (wet weight basis). The weight of the concentrate in kg is __________ (round off to 2 decimal places).

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