How to practice topic:thermodynamic-relations

Attempt a question, record the concept and assumptions, then check the available answer. Rework mistakes after revising the relevant concepts. Topic tags can overlap; review the question context.

Questions 1–10 of 31. Imported answers require independent review unless marked reviewed.

Topic practice 31 questionsPage 1 of 4

Question 97

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XE-EMCQ2 marksNeeds review
Consider a real gas, which obeys the following equation-of-state:

where

is the mass specific volume,

is the pressure,

is the temperature and

is the gas constant.

and

are constants. If

is the mass specific entropy, the quantity

for the gas is given by
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Question 99

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A fluid undergoes a process where its pressure (P), temperature (T) and volume (V) changes from

to

. During the process, volume expansivity (

) and isothermal compressibility (

) remain constant. Given that

and

, the ratio

is
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Question 103

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Consider a single component fluid at saturation conditions having the following properties.
Latent heat of vaporization,

kJ/kmol
Compressibility factor for the vapor phase,


is the saturation pressure

is the temperature

is the molar specific volume of the vapor phase
Assume that

, where

is the difference in the molar specific volume of the vapor and the liquid phases
Universal gas constant,

kJ/kmol-K
Using the Clapeyron equation, the quantity

(in K) is ________ (rounded off to two decimal places).

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Question 104

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It is given that:

and

. Here

is the mass specific enthalpy,

is the mass specific volume,

is the volume expansivity, and

is the mass specific heat capacity at constant pressure.

and

represent the temperature and the pressure, respectively. The inversion temperature is the temperature at which the Joule-Thomson coefficient,

, goes to zero.
Consider a fluid with properties:

m

/kg,

kJ/kg-K, and

1/K;
The inversion temperature (in K) for the fluid is ________ (rounded off to two decimal places).

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Question 99

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Consider a gas obeying the relation

, where b and R are constants. Which of the following statement(s) is/are CORRECT about the specific heat capacity at constant pressure?
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Question 98

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In a graph with Helmholtz function on the

-axis and volume on the

-axis, the slope of the isotherm curves for a finite volume system containing an ideal gas is
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Question 99

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XE-EMCQ2 marksNeeds review
Match each quantity in Column M with the appropriate relation from Column N. Here,

is Helmholtz function,

is pressure,

is specific volume,

is temperature,

is specific enthalpy, and

is specific entropy.
Column M: (M1)

; (M2)

; (M3)

; (M4)

.
Column N: (N1)

; (N2)

; (N3)

; (N4)

; (N5)

; (N6)

; (N7)

; (N8)

.
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Question 102

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The equation of state for a non-ideal gas is

where P is pressure, v is specific volume, R is the specific gas constant, T is temperature, and B is a temperature dependent parameter. For this gas, the partial derivative of enthalpy with respect to pressure at constant temperature is
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Question 106

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The melting point of a substance at 1 bar is 273 K. The following property data is available for this substance at 1 bar.
Property
Value
Density of the solid phase
900 kg/m³
Density of the liquid phase
1000 kg/m³
Latent heat for melting
300 kJ/kg
Assuming that the above properties are constant, the melting point (in K) of the substance at 101 bar is ________ (rounded off to two decimal places).

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Question 93

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Adiabatic bulk modulus of a substance is defined as
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