Question 49

MTNAT2 marksNeeds review
The emf of the cell
Au-Pb(liquid) | PbCl

-KCl(liquid) | Cl

(gas, 0.5 atm), C(graphite)
is 1.2327 V at 873 K. Activity of Pb in the Au-Pb alloy is 0.72 and the activity of PbCl

in the electrolyte is 0.18. The standard Gibbs energy of formation of PbCl

(liquid) at 873 K is ______ kJ·mol

(round off to 1 decimal place).
Given:

and

.

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2022MT

GATE MT 2022 · Paper 1

Metallurgical Engineering · Original paper archive

Section
Metallurgical Engineering
Question type
Numerical answer (NAT)
Marks
2 marks

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